IN ONE SENSE, plastics have been around for millions of years. Plastics are polymers: simple molecular configurations of carbon and hydrogen atoms that link together repeatedly to form chains. Spiders have been spinning polymer fibers called silk since before the Carboniferous Age, whereupon trees appeared and started making cellulose and lignin, also natural polymers. Cotton and rubber are polymers, and we make the stuff ourselves, too, in the form of collagen that comprises, among other things, our fingernails.
Another natural, moldable polymer that closely fits our idea of plastics is the secretion from an Asian scale beetle that we know as shellac. It was the search for an artificial shellac substitute that one day led chemist Leo Baekeland to mix tarry carbolic acid—phenol—with formaldehyde in his garage in Yonkers, New York. Until then, shellac was the only coating available for electric wires and connections. The moldable result became Bakelite. Baekeland became very wealthy, and the world became a very different place.
Chemists were soon busy cracking long hydrocarbon chain molecules of crude petroleum into smaller ones, and mixing these fractionates to see what variations on Baekeland’s first man-made plastic they could produce. Adding chlorine yielded a strong, hardy polymer unlike anything in nature, known today as PVC. Blowing gas into another polymer as it formed created tough, linked bubbles called polystyrene, often known by the brand name Styrofoam. And the continual quest for an artificial silk led to nylon. Sheer nylon stockings revolutionized the apparel industry, and helped to drive acceptance of plastic as a defining achievement of modern life. The intercession of World War II, which diverted most nylon and plastic to the war effort, only made people desire them more.
After 1945, a torrent of products the world had never seen roared into general consumption: acrylic textiles, Plexiglass, polyethylene bottles, polypropylene containers, and “foam rubber” polyurethane toys. Most world-changing of all was transparent packaging, including self-clinging wraps of polyvinyl chloride and polyethylene, which let us see the foods wrapped inside them and kept them preserved longer than ever before.
Within 10 years, the downside to this wonder substance was apparent.
Stanford archaeologist William Rathje, who has made a career of studying garbage in America, finds himself continually disabusing waste-management officials and the general public of what he deems a myth: that plastic is responsible for overflowing landfills across the country. Rathje’s decades-long Garbage Project, wherein students weighed and measured weeks’ worth of residential waste, reported during the 1980s that, contrary to popular belief, plastic accounts for less than 20 percent by volume of buried wastes, in part because it can be compressed more tightly than other refuse. Although increasingly higher percentages of plastic items have been produced since then, Rathje doesn’t expect the proportions to change, because improved manufacturing uses less plastic per soda bottle or disposable wrapper.
The bulk of what’s in landfills, he says, is construction debris and paper products. Newspapers, he claims, again belying a common assumption, don’t biodegrade when buried away from air and water. “That’s why we have 3,000-year-old papyrus scrolls from Egypt. We pull perfectly readable newspapers out of landfills from the 1930s. They’ll be down there for 10,000 years.”
He agrees, though, that plastic embodies our collective guilt over trashing the environment. Something about plastic feels uneasily permanent. The difference may have to do with what happens outside landfills, where a newspaper gets shredded by wind, cracks in sunlight, and dissolves in rain—if it doesn’t burn first.